Investigation of surface tension and surface properties of alkanolamine– alcohol mixtures at T = 313.15 K and P = 90.6 kPa

Investigation of surface tension and surface properties of alkanolamine– alcohol mixtures at T = 313.15 K and P = 90.6 kPa


چاپ صفحه
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صفحه نخست سامانه
چکیده مقاله
چکیده مقاله
نویسندگان
نویسندگان
مؤسسه علوم و صنایع غذایی
مؤسسه علوم و صنایع غذایی

نویسندگان: بی بی مرضیه رضوی زاده , موسی الرضا آبرودی , احمد باقری

نشریه: JOURNAL OF MOLECULAR LIQUIDS , 287 , 110924 , 2019

اطلاعات کلی مقاله
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کد مقاله 1576
عنوان فارسی مقاله Investigation of surface tension and surface properties of alkanolamine– alcohol mixtures at T = 313.15 K and P = 90.6 kPa
عنوان لاتین مقاله Investigation of surface tension and surface properties of alkanolamine– alcohol mixtures at T = 313.15 K and P = 90.6 kPa
نمایه علمی معتبر JCR
IF 4.561
عنوان نشریه JOURNAL OF MOLECULAR LIQUIDS
شماره نشریه 287
دوره 110924
سال انتشار شمسی 1398/05/12
سال انتشار میلادی 2019

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Alkanolamine compounds are especially useful in the adsorption of acid–gases from gas streams. In this work, surface tension for nine binary systems containing an alkanolamine (monoethanolamine (MEA), diethanolamine (DEA) and triethanolamine (TEA)) and a short chain alcohol (methanol, ethanol and isopropanol) were measured over the entire concentration range at 313.15 K and 90.6 kPa by means of the ring detachment method. From these data, the surface tension deviations were computed. The maximum deviation in nine systems was b1%. Then these surface tension datawere correlated using Myers–Scott (MS) and Fu et al. (FLW) polynomial expansions. Also, the surface tension data have been predicted based on the Sprow–Prausnitz (SP) equation. The results show that good agreement is obtained between experimental and predicted data of surface tension, a factwhich confirms the applicability of the SP equation in the binary mixtures with polar components. The modified UNIFAC group contribution method is used for calculation of activity coefficients of components in mentioned systems. Finally, surface mole fraction of alcohol at the (air liquid) interface were calculated from (SP) equations. The results show that the surface concentration of alcohol in binary mixtures increasewith increasing the alkyl chain length of alcohol.

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نویسنده نفر چندم مقاله
بی بی مرضیه رضوی زادهسوم
موسی الرضا آبرودیاول
احمد باقریدوم